Environment Facts, Environment Science
Showing posts with label Biodiesel. Show all posts
Showing posts with label Biodiesel. Show all posts

Tuesday, December 16, 2008

Alternatives to Heating Your Home with Oil or Natural Gas

biodiesel The recent spikes in oil and natural gas prices have put the topic of alternative fuels for home heating at the forefront of discussions around the country. Alternative fuels that in the past were seen as marginal, odd, or strictly for rural use are getting a second look.

Wood heat has been used for generations in the rural U.S., but has been replaced in the past fifty years or so by central heating provided by oil- or gas-fired furnaces. However, in recent years, wood stoves have been making a comeback. Attractive stoves by Jotul and other manufacturers have taken their place in communal living areas like kitchens and living rooms to supplement heating while providing a cozy ambiance to the rooms. Wood furnaces, both internal and external and in many new designs based on the latest technology, provide the ability to load the furnace so as to provide hours of central heating before needing re-stoking. An advantage of burning wood, at least in rural areas, is that it can be locally obtained; people with a wood lot can get it with "sweat equity", and can supplement their income by supplying their neighbors as well.

New plant-based fuels like wood pellets and corn pellets can also provide heat when used in specially designed, clean-burning furnaces and stoves. In addition, more and more people are taking a new look at biodiesel, a fuel manufactured from vegetable oils, primarily soybean oil. Most furnaces can use B20, a fuel made of 80 percent traditional heating oil and 20 percent biodiesel, without any adjustments; some people are getting their furnaces adapted to be able to burn B100, a fuel made entirely of vegetable oils. The biodiesel burns much cleaner than traditional heating oil, but has its own problems (for one thing, biodiesel tends to cause rubber gaskets to erode), so be sure to check with your furnace servicer or manufacturer before you opt for B100.

If you choose to use B100, and your furnace will handle it, you have a couple of options. B100 is becoming more available around the country; check on the Internet to find a supplier near you. Also, waste oil - that is, used vegetable oil discarded by restaurants - can be filtered and used in some furnaces. Several furnaces on the market are designed to burn waste oil. Commercially manufactured B100 has an additive that keeps it liquid at low temperatures, which recycled vegetable doesn't contain, so do your research - and check again with your furnace servicer - before you attempt burning used vegetable oil.

We're facing a new world with lots of challenges in terms of how to heat our homes, especially in colder winter climates. Luckily there are technologies like wood gasification and biodeisel, available today which can help us move away from our decades-old dependence on fossil fuels.

Tuesday, January 29, 2008

How To Go About Biodiesel Production

Muna wa Wanjiru

Biodiesel production is a process of synthesizing biodiesel, it is a liquid fuel source highly compatible with petroleum based diesel fuel. Synthesis is method which is used by manufacturer, in which reaction of a glyceride containing plant with short chain alcohol like methanol or ethanol in a step called as transesterification.

The reaction which occur during this process is below,

Animal and plant fats and oil are made up of triglycerides. There are esters of free fatty acids with tryholic alcohol, glycerol. Here the alcohol is deprotonated with a base to make it stronger nucleophile. Generally in esterfication ethanol or methanol is used. From reaction one can easily find out there us no other input than the triglyceride and alcohol.

This reaction occurs very slowly or may not occur. Acid or base are used to make the reaction more quickly, also can used heat. It is very much important to not that acid or base should not be consumed by esterification reaction. Base catalyzed technique is used for most economical process which requires low temperatures and pressures. It produces more than 98% conversions yield.

Processing Steps

Purification:

If you are using waste vegetable oil, it should be filtered and remove dirt, charred food and other non oil material often food.

Water used to be removed from process because its presence causes the triglycerides to hydorlyze which gives to salts of the fatty acids. It is accomplished by heating the filtered oil approximately 120C. At this temperature any suspended water get boil off. When water gets boils, it used to spitters, so to prevent injury to container, there should be sufficiently large container, they should be closed but not sealed. In laboratory to remove water, they used drying agent like magnesium sulfate.

Neutralization of Fatty acids:

Titration of cleaned oil with standard solution of base which used to make for determines the concentration of free fatty acids (RCOOH) which is present in waste vegetable oil. Base quantity is measure which is required to neutralize the acid.

Transesterfication:

The measured quantity of base used to added slowly to the alcohol. It is then stirred until till it get dissolves. Three full equal size triglyceride are made by adding sufficient alcohol. Excess alcohol is added to complete the reaction.

The solution of sodium hydroxide is being added to a warm solution of waste oil, then the mixture is heated to process transesterification.

Workup:

After completion of reaction glycerol get sink. Emulsion used to occur when ethanol being used. It is being broken by standing, centrifugation, also by addition of low boiling, decanting, distilling. Then the top layer mixture of biodiesel and alcohol is decanted, where the excess of alcohol is distilled off or it is used to extracted through water. Biodiesel should be dried by distillation. It can also be done with the help of drying agent.

Benefits of Process

It is continuous process

It's FAME=98.59 before washing process

It's FAME=99.85 after washing process

It reduces space requirement

It is very low in process inventory

It require minimum manpower

Oils and fats can be produced

Reactors from 1GPM up to 500GPM are available

This process is successful for even poor quality of crude oil.



Muna wa Wanjiru Has Been Researching and Reporting on Biodiesel for Years. For More Information on Biodiesel Production, Visit His Site at BIODIESEL PRODUCTION